Unfortunately, likely due to a false irenicism (condemned by Vatican II), the dogma of papal infallibility has been unduly minimized. The unusual ceremonial attached to the two Marian dogmas have also minimized the other instances. The fact is, Popes have intervened to provided definitive judgments binding the whole Church many, many times.
At the First Vatican Council, when some bishops wanted to condition papal infallibility on the Pope following some procedure, the relator (charged with providing official explanations of Council documents to the bishops at the Council) said this could not be done, because there were already so many instances with various procedures or even none at all:
Bishop Gasser:
But, most eminent and reverend fathers, this proposal simply cannot be accepted because we are not dealing with something new here. Already thousands and thousands of dogmatic judgments have gone forth from the Apostolic See; where is the law which prescribed the form to be observed in such judgments?
“Thousands and thousands” might be a bit hyperbolic, but the point remains–it has been many times. Throughout history Popes have often intervened to provide definitive judgments in the areas of faith and morals, sometimes definitively condemning long lists of propositions (e.g. Coelestis Pastor of Bl. Innocent XI, Ex Omnibus Afflictionibus of St. Pius V, Unigenitus of Clement VI, Auctorem Fidei of Pius VI, etc., etc.; each condemned proposition is probably considered an individual judgment by Gasser above accounting for the high number he gives) and sometimes definitively asserting a truth (e.g. like those definitions in Benedictus Deus of Benedict XII, Unam Sanctam of Boniface VIII, the dogmatic letter of St. Agatho, the Tome of St. Leo, etc.).
Some people ask for a definitive list of definitive judgments by the Pope, but this kind of misses the point. In fact, papal decrees and letters can be lost or forgotten over the course of time. Ordinarily, the ordinary Magisterium of the Church suffices to adequately teach the faith–that is the constant teaching of the true faith by Popes and bishops in their words, letters, catechisms; the belief and handing on of the faith by the faithful in all times and places; in the Church’s worship and traditions, etc. Our faith is not just a list of papal definitions. When the clarity of a truth is cast into doubt (not in the sense that people know what the Church teaches but don’t believe it, but rather in the sense that what the Church actually teaches becomes uncertain) and the ordinary means fail to bring this clarity and unity of faith, it is the duty of the Pope to definitively settle the matter and call all to the unity and clarity of faith–that’s why this exercise of the Magisterium is called extraordinary–so these truths once again can be handed on by the ordinary means throughout the world for ever and ever.