He’s not saying that forms have no cause absolutely speaking. A “substance” (Latin
subsistere, to stand under) has being and operates through itself, as opposed to something which only exists through something else, like shape or color. (How the soul can be said to operate in itself when it requires a body, he explains in
Article 2.)
Another key passage from Q. 75 is in
Article 6, where he says:
[W]hat belongs to a thing by virtue of itself is inseparable from it; but existence belongs to a form, which is an act, by virtue of itself. Wherefore matter acquires actual existence as it acquires the form; while it is corrupted so far as the form is separated from it. But it is impossible for a form to be separated from itself; and therefore it is impossible for a subsistent form to cease to exist.
Again, he’s not saying they have immortality absolutely speaking; their existence still depends on God. But it’s not God’s m.o. to annihilate his rational creatures. And a spiritual being, of its nature, doesn’t decay, age, or die (except in the sense of losing grace).
You may also want to check out
Q. 3 on the simplicity of God, and
Q. 50 on the substance of angels (which, like God, are pure form, but unlike God contain potential as well as actuality).