Although I saw it on the history channel which usually only seems to air shows contrary to our faith I must admit I really enjoyed “The real face of Jesus”.
Not sure what your religious background is like so it may not be necessary for you but you might find The Case for Christ interesting. It’s not Catholic per se but is very interesting for someone learning if they do not have much of a background in Christianity.
DISCLAIMER: Catholic Answers has turned over the archive to Catholic-Questions.org and no longer owns, manages, or moderates the forums. For additional apologetics resources please visit www.catholic.com.