Your friend has the wrong conception of what the “natural” in “natural law” means.
It does not mean simply “occurring in nature.” Otherwise, nothing would be unnatural.
Rather, it means “consistent with the nature of.”
The eyes serve the end of seeing. Eyeglasses enhance this function (or, rather, they correct the deficiencies that impair this function). Therefore, eyeglasses are “natural” in the sense that they are consistent with the nature of eyes, the purpose or end of which is seeing.
Let’s take a different example: sex. Sex makes use of the reproductive system and the reproductive system is ordered by nature toward reproduction. That’s why we have sexual complementarity, strong sex drives (which, for women, often fluctuate according to fertility), etc. Using the reproductive system in a manner consistent with its end is good (since “goodness” in natural law theology is simply “being,” in our case, “being” what we by nature are), so having sex in a manner consistent with the end of procreation is good. That means marital, noncontraceptive, intravaginal, ejaculatory sex. Using it in a way that is contrary to this end (e.g., fornication, contraception, masturbation, intentional withdrawal, etc.) is bad. When done deliberately and with full knowledge or culpable ignorance, it’s a sin.