I think you are right to be concerned that we not ascribe human impulses to God. Ditto emotions. However God, in the person of Jesus, showed us He could be sorrowful, even tearful in grief, indignant and a range of other things. Of course perhaps that was the “fully human” side of Jesus

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But ascribing emotions or impulses to God, I think, does not answer the opening question ~ which was ~ “If we go to church every Sunday does God love us more?”
Eucharisted answered it best and most concisely saying “We go to Mass to love the God who has loved us first”
Here’s the thing ~ we are in one place, living our lives, and God is somewhere else. God’s ways are not (generally) our ways. Many people will go through life picking and choosing a faith or a belief system that appeals to them, that conforms with what they already think or believe.
But that’s not how it works. Our job is not to move God closer to us, to transform God into our image of what God should be. Instead, our job is to move ourselves closer to God, giving up our own, often selfish, ways and live our lives according to God’s will, not our will. Going to Mass on Sunday, or any other day, helps bring us closer to God, helps us deepen our relationship with God, helps us, as Eucharisted said, to love God. The more we love God, the more the rest of all of this falls into place.