Zondervan used to publish a Couples’ Devotional Bible. It was primarily aimed at engaged or newly-wed couples, but I’ve previewed a used copy of it before and didn’t find the contents all that disagreeable for couples even approaching 25 years of marriage. Daily devotional readings are scattered throughout the text with other associated readings.
There’s nothing wrong with starting on page one. What hangs people up is when you start getting into the measurements, censuses and legal minutiae of the later Torah. If you’re not incredibly familiar with the Bible, starting with Genesis 11 and read through to Exodus 24 (skipping Ex 25 through 31) and picking up again would be good for some perspective. Lots of good stories for reflection in those introductory chapters. However, if you’re familiar with the “basic concept,” as it were, then I think the Wisdom literature (Job, Ecclesiastes, Psalms, Proverbs, et. al.) is *prime *material for reflection and prayer.
Also, don’t forget, but the simple act of READING the Bible is a form of prayer, so never feel as if there must be some sort of separate prayer away from it. Not saying not to, but if you’re pressed for time, then reading a Psalm or two would suffice for morning prayer.