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The Church teaches that we are supposed to love our self more than others and that we must care for our souls first and foremost, and that we must love the Lord God and thus all His decrees. God has decreed that those souls in hell suffer punishment there. It would be wrong to give up our precious soul for the damned who are perfectly deserving of hell – God would not put them there if they were undeserving of it and He does not want us there if we are undeserving of it. People in hell belong in hell, it would be wrong for someone to go against God and put oneself in hell so that those deserving of it could be freed from their just torments. God bless you.