This site has many of the quotes from the Bible(see below also). Keep in mind these are just the quotes, anyone will tell you to get the full meaning of what is being said, you should read the whole verse and perhaps verses before and after these.

The CCC gives excellent guidance as well.
scripturecatholic.com/husband_headship.html
"Scripture
The Holy Catholic Church teaches, through Scripture and Tradition, that the husband is the head of his family and has God-given authority over his wife and children. This gift of authority does not give a husband any greater dignity than his wife. Both are equal members of the marital covenant, as is reflected by God creating woman from the side of man (as opposed to his head or feet). Instead, this order of authority reflects the divine order between God, Christ and man. God blessed the marital covenant with this order to maintain peace and harmony in the family, the “domestic church.” Just as Christ is the Head of the Catholic Church (the family of God), so the father is the head of his domestic church (his family).
1 Cor. 11:3 – “But I want you to understand that the head of every man is Christ, the head of a woman is her husband, and the head of Christ is God.”
Eph. 5:22-24 – “Wives, be subject to your husbands, as to the Lord. For the husband is the head of his wife, as Christ is the head of the church, His Body, and is himself its savior. As the church is subject to Christ, so let wives also be subject in everything to their husbands.”
Col. 1:18 – “Wives, be subject to your husbands, as is fitting in the Lord.”
Titus 2:5 – Wives should be submissive to their husbands, that the word of God may not be discredited.
1 Peter 3:1-2 – “Likewise you wives, be submissive to your husbands, so that some, though they do not obey the word, may be won without a word by the behavior of their wives, when they see your reverent and chaste behavior.”
1 Peter 3:5-6 – “So once the holy women who hoped in God used to adorn themselves and were submissive to their husbands, as Sarah obeyed Abraham, calling him lord. And you are now her children if you do right and let nothing terrify you.”
Gen. 2:18; 1 Cor. 11:9; 1 Tim. 2:12-13 – while some people argue that God imposed the submission requirement upon women as a punishment for the original sin, this is not true. God designated the man as the head of his family from the very beginning of creation, even before the original sin. Therefore, man’s authority over the woman was not imposed as a punishment for the original sin, but to reflect the order of creation.
Gen. 3:16 – in fact, God revealed that women would want to usurp their husband’s authority as the result of the original sin. After the original sin, God tells Eve: “Yet your desire shall be for your husband, and he shall rule over you.” Thus, as a result of the original sin, Eve would desire to rule over Adam, but God ensured that Adam would rule over Eve.
Gen. 4:17 – also shows that the Hebrew word for “desire” refers not to a hunger for affection, but a desire to rule over someone. Here, God tells Cain “sin is couching at the door; its desire is for you, but you must master it.” Sin wants to rule over Cain, but Cain must rule over sin.
Isaiah 3:12 – the prophet laments about how women were usurping the authority of men, during the height of Israel’s covenant apostasy.
Just as wives must be submissive to their husbands as the head of the family, husbands must love their wives sacrificially, as Christ loves the Church:
Eph. 5:25,28 – just as wives must submit to their husbands, husbands must “love your wives, as Christ loved the church and gave himself up for her…husbands should love their wives as their own bodies.” Just as the Church is legally and morally obligated to submit to Christ, wives are obligated to submit to their husbands. This is why Paul makes the comparison between husbands and Christ, wives and the Church.
Eph. 5:33 – “let each one of you love his wife as himself.”
Col… 3:19 – “husbands, love your wives, and do not be harsh with them.”
1 Peter 3:7 – “Likewise you husbands, live considerately with your wives, bestowing honor on the woman as the weaker sex, since you are joint heirs of the grace of life, in order that your prayers may not be hindered.”"
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